96. Lei Mei, Qun-yan Wu, Shuwen An, Zeng-qiang Gao, Zhi-fang Chai and Wei-qun Shi*. Silver ion-mediated heterometallic three-fold interpenetrating uranyl-organic framework.
Inorg. Chem. 2015, 54, 10934-10945. (The first two authors contributed equally to this work.)
Synopsis:
A unique case of uranyl-silver heterometallic three-fold interpenetrating network from a multi-functionalized molecule, 2,6-dichloroisonicotinic acid, in the presence of uranyl and silver ions has been prepared. It is combined influences of structural halogenation and silver ion additive on uranyl coordination that plays a vital role in the formation of this network.